Here's one way to do that:
SQL> WITH test AS ( SELECT ename,
2 job,
3 sal empsal,
4 CONNECT_BY_ROOT (sal) bossal
5 FROM emp
6 START WITH ename = 'KING'
7 CONNECT BY PRIOR empno = mgr)
8 SELECT ename,
9 job,
10 empsal,
11 bossal,
12 bossal - empsal diff
13 FROM test;
ENAME JOB EMPSAL BOSSAL DIFF
---------- --------- ---------- ---------- ----------
KING PRESIDENT 5800 5800 0
JONES MANAGER 3775 5800 2025
SCOTT ANALYST 3800 5800 2000
ADAMS CLERK 1900 5800 3900
FORD ANALYST 3800 5800 2000
SMITH CLERK 1600 5800 4200
BLAKE MANAGER 3650 5800 2150
ALLEN SALESMAN 2400 5800 3400
WARD SALESMAN 2050 5800 3750
MARTIN SALESMAN 2050 5800 3750
TURNER SALESMAN 2300 5800 3500
JAMES CLERK 1750 5800 4050
CLARK MANAGER 3250 5800 2550
MILLER CLERK 2100 5800 3700
14 rows selected.
SQL>